ADAPTIVE ABRASIVE COMPOSITES BASED ON PHTHALONITRILE BINDER

  • Eugene Pashchenko Bakul Institute for superhard materials NAS of Ukraine
  • Olga Lazhevska Bakul Institute for superhard materials NAS of Ukraine
  • Denys Savchenko Bakul Institute for superhard materials NAS of Ukraine
  • Oksana Kaidash Bakul Institute for Superhard Materials National Academy of Sciences of Ukraine https://orcid.org/0000-0002-8879-3425
  • Svitlana Kukharenko Bakul Institute for superhard materials NAS of Ukraine
  • Roman Kurganov Bakul Institute for superhard materials NAS of Ukraine
  • Vyacheslav Bychykhin Bakul Institute for superhard materials NAS of Ukraine
  • Sergiy Skorokhod Bakul Institute for superhard materials NAS of Ukraine
  • Nikita Yeltsov Bakul Institute for superhard materials NAS of Ukraine
Keywords: adaptive abrasive composites, adsorption of functional groups, polymer binder, oxide filler

Abstract

An approach to the synthesis of composites capable of adaptive behavior in the contact zone by the mechanism of reverse change in the grafting density of functional groups of the polymer binder to the surface of filler particles is proposed. The influence of technological synthesis parameters and the action of external factors, in particular ultrasonic vibrations, on the degree of the above-mentioned adsorption grafting, and accordingly on the reverse change in the stiffness of the composite, which provides the effect of reaction reinforcement, or adaptation of the abrasive composite during its operation, have been studied. The advantages of the obtained adaptive composites compared to traditional ones in terms of tool performance, wear resistance, and parameters that determine the condition of the processed surfaces are shown.

Author Biography

Oksana Kaidash, Bakul Institute for Superhard Materials National Academy of Sciences of Ukraine

The main area of ​​research is the creation of advanced (high-tech) ceramics with improved physico-mechanical, physico-chemical and functional characteristics due to the establishment of structural sintering mechanisms of refractory carbides and nitrides with heterodesmic interatomic bonds, patterns of formation of their microstructures. Specialist in powder metallurgy and has experience in working with a number of technologies: sintering, hot pressing, slip casting, hot extrusion of ceramic powders.

Leading researcher of dep. 6  ISM NANU, Dr. Sci. (Material Science), 

https://orcid.org/0000–0002–8879–3425;  SCOPUS ID:  6603071054;  h-index: 4

The degree PhD (1992). PhD thesis : "Development of corrosion-resistant cermets based on titanium nitride with increased stability in biologically active medium"  05.02.01 - Material Science 
Defence of thesis 05 December 1991 at the Special Academic Council of the Bakul Institute of Superhard Materials of the National Academy of Sciences of Ukraine (Kyiv).

Dr. Sci. (2019): “Scientific fundamentals of formation of structure and properties during sintering from submicron refractory carbides and nitrides of advanced ceramics for the mechanical engineering” 05.02.01 - Material Science. Defence of thesis 22 November 2018 at the Special Academic Council of the Bakul Institute of Superhard Materials of the National Academy of Sciences of Ukraine (Kyiv).

Published
2025-11-21
Section
Development and implementation of equipment and tools equipped with hard alloys